• Organic Halogen Compounds

  Part 2 - Halogenoalkanes

  In this session, the chapter Organic Halogen Compounds is discussed.

  The following concepts are explained:

       ♦ Sn2 Nucleophilic Substitution Mechanism

       ♦ Carbanion intermediate Structure

       ♦ Reactivity of Primary, Secondary and Tertiary Halogenoalkanes

       ♦ Hydrolysis of Halogenoalkanes - Reaction with NaOH(aq)
   
       ♦ Sn1 and Sn2 Hydrolysis Reactions of Halogenoalkanes
   
       ♦ Reaction with KCN in alcohol

   

       ♦ Sn1 and Sn2 - Reaction with KCN of Halogenoalkanes

   
       ♦ Nitrile formation
   
       ♦ Nitrile hydrolysis and reduction (Reaction with NaBH₄)
   
       ♦ Reaction with concentrated NH₃

   

       ♦ Sn1 and Sn2  Reaction of Halogenoalkanes with Conc. NH₃
   
  The exercise file section contains notes on concepts discussed in this session.

• Session 36: Organic Halogen Compounds - Part 2

  • Halogenoalkanes
    • Sn2 Nucleophilic Substitution Mechanism 5 mins
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      Demo video

      Sn2 Nucleophilic Substitution Mechanism

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    • Sn2 Nucleophilic Substitution Mechanism 2 mins
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      Demo video

      Sn2 Nucleophilic Substitution Mechanism

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    • Reactivity of Halogenoalkanes 4 mins
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      Demo video

      Reactivity of Halogenoalkanes

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    • Hydrolysis Reaction 5 mins
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      Demo video

      Hydrolysis Reaction

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    • Hydrolysis Reaction - Example 2 - Sn1 4 mins
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      Demo video

      Hydrolysis Reaction - Example 2 - Sn1

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    • Reaction with KCN in alcohol 3 mins
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      Demo video

      Reaction with KCN in alcohol

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    • Reaction with KCN - Example 1 - Sn2 5 mins
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      Demo video

      Reaction with KCN - Example 1 - Sn2

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    • Nitrile - Reduction and Hydrolysis 6 mins
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      Demo video

      Nitrile - Reduction and Hydrolysis

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    • Reaction with Ammonia 6 mins
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      Demo video

      Reaction with Ammonia

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    • Reaction with Ammonia - Example 2 - Sn1 4 mins
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      Demo video

      Reaction with Ammonia - Example 2 - Sn1

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• Excercise Files

  • Halogenoalkanes
    • Halogenoalkanes - Part 2 Notes

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